Leachate emissions of short- and long-chain per- and polyfluoralkyl substances (PFASs) from various Norwegian landfills
By Heidi Knutsen, Trond Mæhlum, Ketil Haarstad, Gøril Aasen Slinde, and Hans Peter H. Arp
Environ Sci Process Impacts
August 19, 2019
DOI: 10.1039/c9em00170k
Abstract
Restrictions on the use of long-chain per- and polyfluoralkyl substances (PFASs) has led to substitutions with short-chain PFASs. This study investigated the presence of four short-chain PFASs and twenty-four long-chain PFASs in leachate and sediment from ten Norwegian landfills, including one site in Svalbard, to assess whether short-chain PFASs are more dominant in leachate. PFASs were detected in all sites. Short-chain PFASs were major contributors to the total PFAS leachate concentrations in six of ten landfills, though not in Svalbard. In sediment, long-chain PFASs such as perfluorooctanesulfonate (PFOS) and PFOS-precursors were dominant. Short-chain PFAS leachate concentrations ranged from 68 to 6800 ng L-1 (mean: 980 ± 1800; median: 360 ng L-1), whereas long-chain concentrations ranged from 140 to 2900 ng L-1 (mean: 530 ± 730; median: 290 ng L-1). Sediment concentrations, which contained mainly long-chain PFASs, ranged from 8.5 to 120 μg kg-1 (mean: 47 ± 36; median: 41 μg kg-1). National release from Norwegian landfills to the environment was estimated to be 17 ± 29 kg per year (median: 6.3 kg per year), which is in the same range as national emissions from the US, China and Germany after normalizing the data to a per capita emission factor (3.2 ± 5.5 mg per person per year). Results from this study are compared with previous and current studies in other countries, indicating a general trend that short-chain PFASs are dominating over long-chain PFASs in landfill leachate emissions.
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