Occurrence of perfluoroalkyl substances (PFASs) in marine plastic litter from coastal areas of Central Chile
By Victoria Gómez, Mariett Torres, Pavlina Karásková, Petra Přibylová, Jana Klánová, and Karla Pozo
Mar Pollut Bull
August 25, 2021
DOI: 10.1016/j.marpolbul.2021.112818
Perfluorinated alkyl substances (PFASs) were determined in marine plastic litter (MPL) on six beaches of central Chile. MPL was characterized physically and chemically, showing an abundance of macroplastic (size >2.5 cm). The polypropylene (PP) (47%) was the predominant polymer found. The Desembocadura beach, located at the mouth of the Biobio River, recorded the highest abundance of MPL (3.7 items m-2). PFAS detected (n = 15/21) ranged from 279 to 1211 pg g-1 and accounted for MeFOSE (46%) > PFHxS (14%) > PFPA (11%) > PFBS (6%) > PFOA (4%) and > PFOS (4%). Long-chain PFAS were prevalent, which can be metabolically degraded into PFOS (new POPs). This study i) highlights the need to further investigate the occurrence of chemicals in the MPL to reduce their impact on the environment; and ii) points out the need to improve future coastal management strategies for the elimination of solid waste along the coast of the country.
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